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Aluminum oxide


Solid Phase Heat Capacity (Shomate Equation)

Go To: Top, References, Notes / Error Report

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° - H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 - E/t + F -Dff,298
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 - E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    Df298.15 = enthalpy of formation at 298.15 K (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K)298. - 2327.298. - 2327.298. - 2327.298. - 2327.
A102.4290108.6830106.9180106.0880
B38.7498037.2263036.6219036.33740
C-15.91090-14.20650-13.97590-13.86730
D2.6281812.1936012.1579902.141221
E-3.007551-3.209881-3.157761-3.133231
F-1717.930-1701.600-1710.500-1705.970
G146.9970155.1360151.7920153.9350
Df,298 (kJ/mol)-1675.690-1656.860-1666.490-1662.300
ReferenceChase, 1998Chase, 1998Chase, 1998Chase, 1998
Commenta phase; Data last reviewed in December, 1979g phase; Data last reviewed in December, 1979d phase; Data last reviewed in December, 1979kappa phase; Data last reviewed in December, 1979

Temperature
(K)
Cp
(J/mol*K)

(J/mol*K)
-(G° - H°298.15)/T
(J/mol*K)
H° - H°298.15
(kJ/mol)
298.78.7750.7950.92-0.04
300.79.2851.3250.920.12
400.96.7576.8254.259.03
500.106.199.5161.0919.21
600.112.2119.469.1930.14
700.116.5137.177.6541.59
800.119.9152.886.0853.42
900.122.6167.194.3065.55
1000.124.9180.2102.277.92
1100.126.8192.2109.990.51
1200.128.5203.3117.2103.3
1300.129.9213.6124.2116.2
1400.131.2223.3131.0129.3
1500.132.3232.4137.4142.4
1600.133.3240.9143.6155.7
1700.134.2249.1149.6169.1
1800.135.0256.8155.3182.5
1900.135.8264.1160.9196.1
2000.136.6271.1166.2209.7
2100.137.3277.7171.4223.4
2200.138.0284.1176.3237.2
2300.138.8290.3181.2251.0

Temperature
(K)
Cp
(J/mol*K)

(J/mol*K)
-(G° - H°298.15)/T
(J/mol*K)
H° - H°298.15
(kJ/mol)
298.82.4352.1152.28-0.05
300.82.9752.6752.280.12
400.101.479.3855.779.45
500.111.2103.262.9220.12
600.117.5124.071.4031.57
700.122.0142.580.2643.55
800.125.5159.089.0955.93
900.128.3173.997.7068.63
1000.130.7187.6106.081.58
1100.132.7200.1114.094.75
1200.134.5211.8121.7108.1
1300.136.0222.6129.0121.6
1400.137.3232.7136.1135.3
1500.138.5242.2142.8149.1
1600.139.6251.2149.3163.0
1700.140.6259.7155.6177.0
1800.141.5267.8161.6191.1
1900.142.3275.4167.4205.3
2000.143.1282.8173.0219.6
2100.143.8289.8178.4233.9
2200.144.5296.5183.6248.3
2300.145.2302.9188.6262.8

Temperature
(K)
Cp
(J/mol*K)

(J/mol*K)
-(G° - H°298.15)/T
(J/mol*K)
H° - H°298.15
(kJ/mol)
298.81.0950.4450.59-0.04
300.81.6250.9950.590.12
400.99.7377.2754.039.30
500.109.4100.761.0619.79
600.115.6121.269.4131.06
700.120.0139.378.1342.85
800.123.4155.686.8155.03
900.126.2170.395.2867.51
1000.128.6183.7103.580.26
1100.130.6196.1111.393.22
1200.132.3207.5118.9106.4
1300.133.8218.2126.1119.7
1400.135.1228.1133.0133.1
1500.136.3237.5139.7146.7
1600.137.3246.3146.1160.4
1700.138.3254.7152.2174.1
1800.139.2262.6158.1188.0
1900.140.0270.1163.8202.0
2000.140.7277.3169.3216.0
2100.141.5284.2174.6230.1
2200.142.2290.8179.8244.3
2300.142.9297.2184.7258.6

Temperature
(K)
Cp
(J/mol*K)

(J/mol*K)
-(G° - H°298.15)/T
(J/mol*K)
H° - H°298.15
(kJ/mol)
298.80.4653.3753.53-0.05
300.80.9953.9153.530.12
400.98.9679.9956.939.22
500.108.5103.263.9119.64
600.114.7123.672.1930.82
700.119.1141.680.8442.51
800.122.5157.789.4654.60
900.125.3172.397.8766.99
1000.127.6185.6106.079.63
1100.129.5197.9113.892.49
1200.131.2209.2121.3105.5
1300.132.7219.8128.5118.7
1400.134.1229.7135.3132.1
1500.135.2239.0141.9145.5
1600.136.3247.7148.3159.1
1700.137.2256.0154.4172.8
1800.138.1263.9160.2186.6
1900.138.9271.4165.9200.4
2000.139.6278.5171.3214.3
2100.140.4285.3176.6228.3
2200.141.1291.9181.7242.4
2300.141.8298.2186.6256.5

References

Go To: Top, Solid Phase Heat Capacity (Shomate Equation), Notes / Error Report

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951.  [all data]


Notes / Error Report

Go To: Top, Solid Phase Heat Capacity (Shomate Equation), References

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